Formulas For Thermochemistry
q = C x ∆t
Where C = heat capacity(J/ºC), and ∆t = the change in temperature (final - initial)
q = m x c x ∆t
Heat flow; Where m = mass, c = specific heat, and ∆t = change in temperature (final - initial)
Specific Heat of H₂O
4.18 J/gºC
q reaction = -q calorimeter
Represents how the heat flow for the reaction system is equal in magnitude but opp in sign to that of the calorimeter
q reaction = -C cal x ∆t
Bomb calorimeter; This can be used to find the amt of heat absorbed/evolved in a reaction if you know the heat capacity (C cal), and ∆t = change in temperature
∆H = ∆H₁ + ∆H₂
Hess's law in which ∆H must equal the sum of ∆H₁ + ∆H₂
q reaction at constant pressure = ∆H = H products - H reactants
Difference in enthalpy is equal to the heat flow for the reaction system
∆Hº = ∑∆Hºf products - ∑∆Hºf reactants
Standard enthalpy change; Finding the enthalpy of formation
∆E system = -∆E surroundings
Law of conservation of energy
∆E = q + w
First law of thermodynamics; Total change in energy equal to the sum of work and heat flow
∆H = qp
Heat flow at constant pressure is equal to change in enthalpy
∆H = qv
Heat flow at constant volume is equal to change in enthalpy
∆H = ∆E + ∆(PV)
Change in enthalpy is equal to the sum of change in energy and the change in the product of PV
∆H = ∆E + ∆ngRT
∆H vs. ∆E; Change in enthalpy is equal to the sum of change in energy and the product of the change in the number of moles of gas and RT where R = 8.31 J/mol K and and T is in kelvin